If the OneDrive for Business desktop client supported the synchronization of multiple libraries at once, that would help a lot of people. I'm speaking of different organizational libraries with differing credentials within a single Windows environment. This request has been discussed in the following threads:

https://community.office365.com/en-us/f/154/t/432695

https://community.office365.com/en-us/f/172/t/271401?pi14985=1