I’m going to open this one back up. We are working to add support to filter the Android photos view to include all photos or those only in the Pictures folder, for all users not only for Samsung Gallery Sync customers.
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How ? I dont see any option to do this...
We’ve heard the feedback and are going to have the option to control what content shows up in the photos tab in the mobile app. We allow you to change this setting on OneDrive.com today.